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phenylboronic acid

CAS No. 98-80-6 | Catalog No. 655547


Synonyms
Benzeneboronic acid; Dihydroxyphenylborane; NSC 66487; Phenyl-boric acid; Phenylboric acid; Phenyldihydroxyborane


Properties

Melting Point 216-219 °C(lit.)

Application
It may be employed in the following reactions:• Rhodium-catalyzed intramolecular amination.• Pd-catalyzed direct arylation.• Mizoroki-Heck and Suzuki-Miyaura coupling reactions catalyzed by palladium nanoparticles.• Palladium-catalyzed stereoselective Heck-type reaction.• Highly effective Palladium-catalyzed arylation Suzuki-Miyaura cross-coupling in water.It may be employed as reagent in the preparation of:• Ni(II) pincer complex and Pd(II) pyridoxal hydrazone metallacycles as catalysts for the Suzuki-Miyaura cross-coupling reactions.• N-type polymers for all-polymer solar cells.• Novel series of potent and selective mTOR kinase inhibitors.• Inhibitors of lactate dehydrogenase against cancer cell proliferation.


General Description
PBA is an organoboronic acid. It behaves as a molecular receptor that can attach to compounds containing cis-diol group. Microwave-assisted Suzuki coupling of aryl chlorides in the presence of Pd/C (catalyst) and water (solvent) has been described. Palladium-catalyzed cross-coupling reaction of phenylboronicacid with haloarenes to afford biaryls has been reported.

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