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phenylethynyltrimethylsilane

CAS No. 6-1-70 | Catalog No. 655372


Synonyms
1-Phenyl-2-trimethylsilylacetylene;1-(Trimethylsilyl)-2-phenylacetylene; Phenylethynyl-trimethylsilane; Trimethyl(phenylethynyl)silane;1-PHENYL-2-TRIMETHYLSILYLACETYLENE 99%;2-Phenyl-1-(trimethylsilyl)acetylene;2-Phenyl-1-ethynyltrimethylsilane;Phenyl(trimethylsilyl)ethyne;Benzene; [2-(trimethylsilyl)ethynyl]-;Silane; trimethyl(phenylethynyl);[2-(Trimethylsilyl)ethynyl]benzene


Properties

Boiling Point 87-88 °C9 mm Hg(lit.)

Application
It was used in the preparation of donor-stabilized Pt-η-alkyne complexes. It was used in the preparation of donor-stabilized Pt-η2-alkyne complexes.


General Description
It is an SiMe3-substituted alkyne. It undergoes coupling with propargylic and allylic alcohols. Polymerization of 1-phenyl-2-trimethylsilylacetylene by various transition metal catalysts has been reported.

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