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trimethylsilyl isocyanate

CAS No. 1118-02-01 | Catalog No. 655392


Synonyms
trimethylsilanylisocyanate;ISOCYANATOTRIMETHYLSILANE;Silane;isocyanatotriMethyl-


Properties

Boiling Point 90-92 °C(lit.)
Melting Point -49°C
Solubility Miscible with ethers and o-dichlorobenzene.

Application
It is used in the preparation of 1-unsubstituted 4-(dialkylamino) imidazolin-2-ones. It finds application in the carbamoylation of aromatic hydrocarbons and alcohols. It is also used in the preparation of primary amides from Grignard reagents. Further; it is used in the synthesis of cyclic imides. It is also utilized for the synthesis of trifluoroacetyl isocyanate and cyclic imides. In addition to this; it is employed in the conversion of isocyanates to carbodiimides using cyclopentadienyl Mn(CO)3 catalysis. It was used in: • postsynthetic modification of isoreticular metal-organic framework-3 • synthesis of 1-unsubstituted 4-(dialkylamino) imidazolin-2-ones • conversion of isocyanates to carbodiimides with cyclopentadienyl Fe(CO)2 or -Mn(CO)3 catalysis • carbamoylation of aromatic hydrocarbons and alcohols

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